虎扑电竞 虎扑电竞

A group of researchers has recently unveiled a novel mechanism that leads to further suppression of thermal conductivity in thermoelectric materials, something that will help develop new guidelines for producing high-performance thermoelectric materials.

Details of their research were published in the journal Advanced Materials on December 17, 2022.

Controlling the ease with which heat is transmitted through a material, i.e., thermal conductivity, has a wide range of applications to our everyday lives: from insulating our homes, to improving the performance of electronic devices, as well as enhancing the energy conservation of automobiles and aviation and generating greater power efficiency.

Scientists are increasingly interested in thermal management technology as a means to solve various heat-related problems and to effectively utilize thermal energy.

When the research group placed atomic chains into tunnel spaces within intermetallic compound crystal structures, the atoms strongly correlated with each other in large amplitude vibrations, or "rattling." Vigorous experiments and theoretical calculations demonstrated that the stronger the correlation between rattling atoms, the greater the decrease in thermal conductivity.

"Since advancements in thermoelectric materials require lower thermal conductivity, our discovery can provide new guidelines for engineering improved thermoelectric materials," states Takahiro Yamada, professor at Tohoku University's Institute of Multidisciplinary 虎扑电竞 for Advanced Materials (IMRAM) and co-author of the paper.

Also involved in the group was Professor Hisanori Yamane, also from IMRAM, Dr Masahiro Kanno from Tohoku University's Graduate School of Engineering (at the time of research), Professor Masato Yoshiya from Osaka University's Graduate School of Engineering, Associate Professor Hiroshi Takatsu and Professor Hiroshi Kageyama from Kyoto University's Graduate School of Engineering, Chief Senior 虎扑电竞 Scientist Dr Takuji Ikeda from the National Institute of Advanced Industrial Science and Technology's (AIST) 虎扑电竞 Institute for Chemical Process Technology, and Senior 虎扑电竞 Scientist Dr Hideaki Nagai from AIST's 虎扑电竞 Institute for Energy Conservation.

Publication Details:

Title: Correlated rattling of sodium-chains suppressing thermal conduction in thermoelectric stannides
Authors: Takahiro Yamada, Masato Yoshiya, Masahiro Kanno, Hiroshi Takatsu, Takuji Ikeda, Hideaki Nagai, Hisanori Yamane, and Hiroshi Kageyama
Journal: Advanced Materials
DOI: 10.1002/adma.202207646

Press release in Japanese